Synthesis and Properties of Aromatic Compounds

External reference: https://openalex.org/T11298

  1. Desymmetrization method forms N–N atropisomers with multiple stereocenters
    Asymmetric Michael addition constructs N-N atropisomers from indole-derived maleimides with simultaneous generation of multiple stereocenters, achieving 99% yield and exceptional stereoselectivity.
  2. Tetraethynyl DOTs show π-stacking and n-type semiconductor behavior
    Tetraethynyl dioxotriangulene derivatives synthesized via C–O activation demonstrate n-type semiconductor properties through π-stacking and radical anion stabilization in field-effect transistors.