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Aryl Halide Carboxylation via Decarboxylative Metal–Halogen Exchange
Novel decarboxylative metal-halogen exchange mechanism enables mild carboxylation of aryl halides using bench-stable potassium carboxylate salts without pressurized equipment or organometallic.
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Three-layer strategy rapidly produces fused hydantoins and diketopiperazines
A scalable three-layer synthesis strategy rapidly produces thiazolo-hydantoins and diketopiperazines in under 3 hours without chromatography, enabling one-pot processing and late-stage modification.
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Photocatalysis enables synthesis of trifluoromethyl amidines and imidates
Photocatalytic metal-free synthesis of α-trifluoromethyl amidines and imidates using isocyanides and trifluoroacetylsilanes, with mechanistic insights from DFT studies.
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Light-induced CO2 binding and reduction in a cerium MOF
Cerium metal-organic framework with amino linkers achieves 100% selective photoreduction of CO2 to CO at 126 μmol·g-1·h-1 via transient Ce(III) sites and reversible binding.
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Dog detection outperformed humans in avian carcass surveys
Experimental comparison of avian carcass detection by human surveyors and conservation dog reveals higher canine detection probability influenced by carcass size and substrate complexity.
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Bora links Aurora-A activation to PLK1 recognition
Structural analysis revealing how the intrinsically disordered protein Bora bridges Aurora-A kinase and PLK1 substrate recognition through phosphorylation-dependent mechanisms during mitotic entry.
