-
Organocatalytic CDC adds fluoronitromethane to tetrahydroisoquinolines
Organocatalytic cross-dehydrogenative coupling of tetrahydroisoquinolines with fluoronitromethane using Rose Bengal and green LED irradiation for sustainable fluorinated compound synthesis.
-
Organophotoredox alkylation expands access to SF5-containing aliphatic molecules
Metal-free organophotoredox catalysis enables efficient alkylation of vinylsulfur pentafluoride to synthesize SF5-containing aliphatic molecules under mild conditions with broad functional group.
-
Three-layer strategy rapidly produces fused hydantoins and diketopiperazines
A scalable three-layer synthesis strategy rapidly produces thiazolo-hydantoins and diketopiperazines in under 3 hours without chromatography, enabling one-pot processing and late-stage modification.
-
Modular synthesis of CF3/CHF2 dihydroquinoline sulfonyl fluorides
Modular synthesis of CF3/CHF2-substituted dihydroquinoline sulfonyl fluorides via [4+2] cycloaddition and sulfur(VI) fluoride exchange without transition metal catalysis.
-
THF increased yields of polyfluorinated tetraketones
Synthesis of polyfluorinated diketoesters and tetraketones from perfluorinated dicarboxylic acid esters and alkyl ketones, with mechanistic investigation via MP2 calculations.
