Porphyrin

  1. New fused NiII porphyrin dimers were synthesized
    Synthesis of fused-azepine- and 1H-azocine-bridged NiII porphyrin dimers via Pictet-Spengler cyclization and oxidative transformations, yielding NIR-absorbing and fluorescent complexes.
  2. Visible-light photocatalyst achieves near-complete PFAS defluorination
    Visible-light photocatalytic defluorination of PFAS using stabilized porphyrin radicals achieving near-complete conversion without additives.