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Organophotoredox alkylation expands access to SF5-containing aliphatic molecules
Metal-free organophotoredox catalysis enables efficient alkylation of vinylsulfur pentafluoride to synthesize SF5-containing aliphatic molecules under mild conditions with broad functional group.
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Ultrathin chiral nanosheets improved gas chromatography separations
Ultrathin 2D nanosheets from exfoliated chiral ionic organic crystals enable high-resolution gas chromatography with exceptional enantioselectivity for pharmaceutical compound separation.
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DOM forms PFAS nanoclusters and lowers phytotoxicity
In situ AFM reveals DOM-induced PFAS nanoclustering reduces phytotoxicity through altered bioaccessibility, challenging molecular dispersal-based risk paradigms.
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Cryo-EM shows multiple cytochrome P450 reductase conformations
3.3 Å cryo-EM of full-length rat cytochrome P450 reductase reveals a relaxed compact state, additional compact variants, and ~20% of particles with displaced or missing FMN domain.