Focal Interest
Focal Interest

Inorganic Fluorides and Related Compounds

External reference: https://openalex.org/T12646

  1. Trifluoromethyl copper complexes were repurposed for saccharide difluoromethylation
    Photo- and acid-mediated repurposing of Grushin's reagent enables efficient difluoromethylation of alcohols, saccharides, and bioactive molecules, generating antifungal leads.
  2. Chemical recycling of hydrofluorocarbons by transfer fluorination
    Chemical recycling method converts hydrofluorocarbons into usable fluoride sources through transfer fluorination, enabling synthesis of diverse fluorinated molecules at industrial scale.
  3. In situ sensors enable simultaneous hydrogen and oxygen detection
    Real-time sensor platform for simultaneous H2 and O2 detection in photocatalytic water splitting, enabling kinetic characterization without conventional gas chromatography limitations.
  4. New XeF2 adduct cations with PdIV and PtIV were identified
    Synthesis and characterization of novel [PdF3(XeF2)3]+ and [PtF3(XeF2)3]+ adduct cations represents a new class of XeF2 coordination compounds to fluoridometal cations.
  5. Photoredox method enables deoxytrifluoromethoxylation of phenols
    Photoredox-catalyzed deoxytrifluoromethoxylation installs OCF3 groups on phenols via in situ difluorophosgene generation and aryl carbonofluoridate activation.