Focal Interest
Focal Interest

Halide

  1. Aryl Halide Carboxylation via Decarboxylative Metal–Halogen Exchange
    Novel decarboxylative metal-halogen exchange mechanism enables mild carboxylation of aryl halides using bench-stable potassium carboxylate salts without pressurized equipment or organometallic.
  2. New sulfanyl indeno triazinones were synthesized and some cyclized further
    Novel one-pot synthesis of 3-alkenyl(propargyl)sulfanyl-indeno[1,2-e][1,2,4]triazin-9-ones with selective heterocyclization through halogenation.
  3. 2-Lithiomethylindoles enable diverse 2-functionalized indoles
    Optimized α-lithiation protocol for 1,2-dimethylindoles enables efficient C2-functionalization via diverse electrophile trapping in deep eutectic solvents under air-tolerant conditions.