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Organophotoredox alkylation expands access to SF5-containing aliphatic molecules
Metal-free organophotoredox catalysis enables efficient alkylation of vinylsulfur pentafluoride to synthesize SF5-containing aliphatic molecules under mild conditions with broad functional group.
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Additive radii fitted for sixfold metal–metal bonding
Additive covalent radii for sixfold metal-metal bonded dimers across transition metals and actinides with 12 valence electrons in (1σ)²(2σ)²π⁴δ⁴ configuration.
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Stereochemical assignment of trifluoroacetamides using NMR signals
Stereochemical assignment of N,N-dialkyl trifluoroacetamides using integrated analysis of through-space 1H···19F spin-spin couplings and aromatic solvent-induced shifts in 1H-NMR spectroscopy.
