Electron paramagnetic resonance

  1. Light-induced CO2 binding and reduction in a cerium MOF
    Cerium metal-organic framework with amino linkers achieves 100% selective photoreduction of CO2 to CO at 126 μmol·g-1·h-1 via transient Ce(III) sites and reversible binding.
  2. Tetraethynyl DOTs show π-stacking and n-type semiconductor behavior
    Tetraethynyl dioxotriangulene derivatives synthesized via C–O activation demonstrate n-type semiconductor properties through π-stacking and radical anion stabilization in field-effect transistors.