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Photocatalysis enables synthesis of trifluoromethyl amidines and imidates
Photocatalytic metal-free synthesis of α-trifluoromethyl amidines and imidates using isocyanides and trifluoroacetylsilanes, with mechanistic insights from DFT studies.
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Cyclometalated platinum products depend on the halogen in the ligand
Study of cyclometalated platinum compounds formed via competing C-H and C-X bond activation pathways, with mechanistic insights from computational and spectroscopic analysis.
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Tetraethynyl DOTs show π-stacking and n-type semiconductor behavior
Tetraethynyl dioxotriangulene derivatives synthesized via C–O activation demonstrate n-type semiconductor properties through π-stacking and radical anion stabilization in field-effect transistors.
