Focal Interest
Focal Interest

Cascade

  1. Organocatalytic CDC adds fluoronitromethane to tetrahydroisoquinolines
    Organocatalytic cross-dehydrogenative coupling of tetrahydroisoquinolines with fluoronitromethane using Rose Bengal and green LED irradiation for sustainable fluorinated compound synthesis.
  2. Structure-preserving simulations show differing turbulence behavior
    Structure-preserving simulations of three magnetohydrodynamics models reveal divergent cascade mechanisms and vorticity dynamics despite shared Hamiltonian geometry.
  3. Indoles converted to α-perfluoroalkylamino derivatives under mild conditions
    Novel sequential perfluoroalkylation and defluoroamination of indoles via sulfinate-derived radicals and HMDS-mediated C-F cleavage, yielding α-trifluoromethylated amines in up to 80% yield.